My heat riser was really stuck as well, but in the closed position. This is while the manifold is on the car, going through heat and cold cycles. I soaked it repeatedly with PB Blaster, and also purchased Mopar Rust Penetrant based on comments of folks on this forum. It wouldn't budge. I finally got it to move when I got frustrated and really leaned into it. It moved just a bit at first, but after working back and forth a bunch it finally freed up. You can leave it as is on your car since it's frozen open and it'll only affect cold weather start performance, but if you keep at it you might get yours to free up.