New water pump? I am sure you got this. But you might try this. Remove thermostat, a fill with phosphoric acid and water mix, CLR was just that mix, not sure if it still has phosphoric acid in it. Up here in Ontario it was removed.
I buy jug of concentrated phosphoric acid for my derusting tank, a little goes along way.
You might have had lots of air trapped in block and with the sediment causing your violent boil over.
Run it just long enough with the mix to circulate through block, leave it 6 hours or overnight like 10 hrs max. start engine and flush, I garden hose connection flowing into block will help.
Keep running and sitting till clear water.
This might lead to frost plugs being pulled and block cleaned that way.
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