I know this thread is a year old, but I am going through the same exact problem with the same exact carburetor.
I kept noticing my '66 was easy to start cold, but took too long to start with it heat soaked. I parked it in the garage right after a drive, then came back out about 30 minutes later to strong gasoline fumes in the engine bay. I pulled off the air cleaner, and fuel had dripped out of the accelerator pump discharge and was even present in the primary venturi high speed air bleeds. It had been dripping off the throttle shaft on to the intake as well. Leaning in, I could hear the fuel percolating slightly. This carb was freshly rebuilt top to bottom not long ago and works well otherwise.
I disagree with the electronic ignition suggestions. I have a '68 Valiant with a slant six that is completely stock. I drove it 7 days straight during hot weather in addition to numerous trips around town at other times and it never failed to start or run perfectly with it's points ignition, so that isn't the answer. CHRYSLER'S answer for the hot start BS was to increase the cranking speed by fitting a larger starter. I did that in a fashion by swapping in my rare 2098500 starter that spins faster. However, that is still a bandaid to the symptom and not a cure.
So, evidently, these AFB carbs by design are prone to horrible heat transfer, probably because of the one piece design with no gasket between the bowl and baseplate. You remember that Carter phased out that design after '71 and went to the Thermoquad with a separate, phenolic bowl. I guess they knew something we don't.
What I believe is happening is that the carburetor is getting too hot, and the fuel is boiling after shutdown. In ADDITION, since the floats are light and not connected to each other, they are bouncing in the boiling fuel and letting the needle valves open and shut, admitting too much fuel. That's where the overrun into the intake is coming from, because a set quantity of fuel, even if it is boiling, should not increase in volume...it should simply be more prone to evaporation.
Ok, so what is the cure for a carburetor that wants to act like a big heat sink? Different gas? Everyone wants to blame it on that, but I have a 350 Chevy that runs fine on it, the previously mentioned slant, and a 318 smogger that also runs fine on the ethyl gas.
I think the key is to :
1. lower the carb temperature. The OP's question about a spacer was only vaguely answered. Summit has one that is called "early AFB", but I doubt it will fit, because the Mopar early AFB is a smaller size than almost everything afterward...it's like an early Buick or Caddy carb. So, again, does anyone have a part number for the right item?
2. control the needle valves. Fortunately, Edelbrock sells spring-loaded needle and seat assemblies designed for off-road and marine applications which help keep the inlets closed with the floats bouncing around. Again, probably a shortcoming found later.
I'm going to work on this issue and will report back with success or failure. If it is failure and i just can't get this carb to work well when it is hot, I will evaluate swapping the intake and carb for something else, since I intend to drive my car without issues. Thanks.