Not really thinner, but yes they were starting to run out of real estate with the 4.84 spacing, so straight is very important or so they thought. The 4.50 bore Siamese blocks proved you really don't need that flow all the way around.
Chrysler developed the new casting technology for the 273 engine that was for its day, a very compact design. Previous castings had lots of extra metal to compensate for bore migration. Keeping the bores straight took less casting material to maintain the integrity of the bores. This led to an immediate benefit as the 413 could be up sized to 426 and the 361 could be up sized to 383. Further refinements in this technology allowed the creation of the 440 in the same RB block.
Dave