Basically, thermostat temps at the t/stat housing, upper radiator hose, and engine block. Possibly similar at the lower hose and water pump housing. The heat gun is also handy to see which parts, if not all, of the radiator core are hot, too. The exhaust manifold runners will be over 500 degrees F, so the area on the cyl head might have some bleed-over from the exh flow, as the inside of the head would not. Similar with the exh heat in the head crossover under the plenum area of the intake manifold.