On the air pump systems, the air pump output goes to its various places under the hood via rubber hoses and valves. Other than the external plumbing which GM and Ford used, I recall that Chrysler put their air to the exhaust manifold via the front of the manifold itself, rather than to the individual runners in the exhaust manifold? BUT if one of the "one-way valves" goes bad, it can let exhaust gas get past these valves and further upstream toward the pump and diverter valve. Usually, though, some additional exhaust noise is evident when this happens, plus the rubber itself can melt/degrade from the exhaust heat it was not designed to tolerate.
The one-way valves can be somewhat "common" between the OEMs, but the diverter valves and items upstream might not be.
The OTHER thing is that if the engine is properly tuned, hydrocarbon output should be greatly decreased from prior times, which also minimizes any smells out of the exhaust system, by observation. As a check, with the engine at full operating temperature (after driving about 10 miles on the freeway), you can momentarily place the palm of your hand in the exhaust output for a few seconds (it will be HOT). Then immediately compare the smell from your hand to that which is getting inside the car. Same or different? Using that method is how I used to verify the carb idle mixture on my cars, plus the idle speed in gear for smoothness. So I know it can work, but only one exposure between handwashings, as the smell lingered a while. Also, be sure to fully wash your hands afterward, so any "nasties" in the exhaust gas aren't absorbed into your skin!
What about any engine/transmission oil leaks which might be hitting the hot exhaust system, generating "smoke or smells" which can get into the passenger compartment? Just curious.
Please keep us posted on your progress,
CBODY67