Remind me - is this the V shaped belt-load-tightening P.S. bracket? These brackets are misunderstood, and the issue has been brought up a few times here. They're actually pretty decent if they're properly assembled and maintained.
However, and at any rate, I do not think there should be a wear groove as seen on yours under the bolt's head and near the threads. Now ( and I'm going on memory here), IIRC, both the head and the threaded end should be very snug against the outside of both sides of the OUTER V -bracket (the "nut" for the bolt being integral to the V bracket) squeezing against but NOT binding the inner V-bracket.
Alignment is helped by the rubber snubber at the bottom of the V. If it's not there the bracket can twist, and this allows for the bolt to get wear patterns as seen, and the holes in the brackets to become hogged out, all of which exacerbates the misalignment. If the holes aren't too bad, then the situation is easily repaired either a new snubber, and if the twist is set, more alignment solutions are to be found by shimming the pump to the bracket with washers. I'll post some pics later.
Edit - apparently these V brackets are also in repro, or at least can be bought "refurbished" with new parts etc but I can't find a link to the service.
HOWEVER, if originality is not a requirement, there is a MUCH better 2 pc bracket out there that retains original belt alignment and never moves. In the old days one had to find it on 68 and up big block cars originally so equipped, but now it's being reproduced.
Pictures to follow.
UPDATE: Pictures:
USING WASHERS TO DEAL WITH ALIGNMENT ISSUES ON BRACKETS THAT HAVE A TWIST SET INTO THEM FROM PREVIOUS "NO SNUBBER" AND MILD BOLT HOLE WEAR
EXTRA STRONG FACTORY IMPROVED 2 PC MOUNTING BRACKET
This can be bought here:
TRW Power Steering Pump Brackets